L-Glutamic Acid → HCID 54012869, compound

HRID 438010Notes

Reaction equation

HRID 438010 reaction equation
O=[CH:2][C@@H:3]([C@@H:5]([C@@H:7]([CH2:9][OH:10])[OH:8])[OH:6])[OH:4].[NH2:11][C@H:12]([C:18]([OH:20])=[O:19])[CH2:13][CH2:14][C:15]([OH:17])=[O:16]>[Ni]>[OH:4][CH:3]([CH:5]([OH:6])[CH:7]([OH:8])[CH2:9][OH:10])[CH2:2][NH:11][C@H:12]([C:18]([OH:20])=[O:19])[CH2:13][CH2:14][C:15]([OH:17])=[O:16]

Participants

4

Reactant 2

HCID 33032L-Glutamic AcidHCID 5311110Aldehydo-D-ribose

Product 1

HCID 54012869HCID 54012869, compound

Reagents, catalysts & solvents 1

HCID 935NickelCatalyst

Procedure

The product was made from D-ribose and L-(+)-glutamic acid using Raney nickel as a catalyst under the conditions of the above examples. A resin-like product was obtained with a RF -value of 0.80 (determined as indicated under Example M).

Workup

  1. customA resin-like product was obtained with a RF -value of 0.80 (determined as indicated under Example M)

Sources & evidence

ORD record
ord-c96a52f70b1e43f8964b60306705f4e0
Source dataset
uspto-grants-1977_06
Patent number
US04032676

Reaction notes

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