HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 438031Generated: October 27, 2026
Butanal → Diphenyl-1-(p-tolylsulfonylamino)butylphosphine oxide
https://huagongshe.com/reaction/438031
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Butanal | HCID 261 | — |
| Reactant | P-Toluenesulfonamide | HCID 6269 | — |
| Reactant | Phenoxydiphenylphosphine | HCID 11543680 | — |
| Solvent | Chlorobenzene | HCID 7964 | — |
| Product | Diphenyl-1-(p-tolylsulfonylamino)butylphosphine oxide | HCID 21427381 | — |
Reaction Steps
A white solid (60.6 g, 71% yield) separates when a mixture of 0.2 mole each of phenyl diphenylphosphinite, n-butyraldehyde, and p-toluenesulfonamide in 125 g of chlorobenzene is warmed at 105° C. for 1 hr. Recrystallization three times from o-dichlorobenzene gives a white solid product: mp 254°-263°; 31P nmr (CF3CO2H)- 44.7 ppm.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04032601 |
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| Source dataset | uspto-grants-1977_06 |
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| ORD ID | ord-1469bfab5735472baa070acfa627cd1f |
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| Source note | uspto-grants-1977_06 |
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