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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 440182Generated: October 26, 2026

Chlorotrimethylsilane → Silane, trimethyl(trifluoroethenyl)-

https://huagongshe.com/reaction/440182

Reaction equation

Participants

RoleNameHCIDCharge
ReactantChlorotrimethylsilaneHCID 6397—
ReactantChlorotrifluoroethyleneHCID 6594—
ReactantButyllithiumHCID 178418339—
ProductSilane, trimethyl(trifluoroethenyl)-HCID 11205884—

Reaction Steps

Chlorotrifluoroethylene of the formula (7) is treated with n-butyl lithium and then reacted with chlorotrimethylsilane of the formula (8) to obtain 1,1,2-trifluoro-2-trimethylsilylethylene of the formula (9). Then, without isolation, this compound (9) is reacted further with a lithium compound of the formula (10) to obtain a difluoroethylene compound of the formula (11).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS05516949
Source datasetuspto-grants-1996_05
ORD IDord-81f4e5c0251d4fa980836e89a829f84c
Source noteuspto-grants-1996_05