HRID440375

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID280

Carbon dioxide

CO2

HCID957

1-Octanol

C8H18O

$结构：CCCCCCCC/C=C\CCCCCCCC(=O)O$

HCID445639

Oleic acid

C18H34O2

HCID9855530

未命名化合物

PRODUCTS

生成物

$结构：CCCCCCCC/C=C\CCCCCCCC(=O)[O-].CCCCCCCC/C=C\CCCCCCCC(=O)[O-].O=C([O-])[O-].[Ba+2]$

HCID86746142

未命名化合物

收率 21%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID962

Water

H2O

2 次

CONDITIONS

反应条件

温度: 190 °C

PROCEDURE

实验过程

To a mixture of 50 g of octanol and 150 g of process oil (PUREXX12 : Esso Petroleum) was added 122 g of barium oxide gradually to disperse it, 24 g of water and 117 g of oleic acid were added, the mixture was stirred for 30 minutes, and carbon dioxide (20 L/hour) was blown thereinto at 130° C. for 3 hours to progress reaction. The mixture was gradually heated to 190° C. to continue reaction while water was distilled off, and then filtered to give a brown solution of an overbased barium oleate-carbonate complex (Ba=21%; metal ratio=3.4) (this product is designated S-2).

WORKUP

后处理

additionwere added
waitat 130° C. for 3 hours to progress
customreaction
distillationwas distilled off
filtrationfiltered

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-575d17ef3706487d8dcb4ba1ad6996d8
来源数据集: uspto-grants-1996_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05519076
来源说明: uspto-grants-1996_05

反应 SMILES

C([OH:9])CCCCCCC.[O-2].[Ba+2:11].[C:12]([OH:31])(=[O:30])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29].[C:32](=[O:34])=[O:33]>O>[C:12]([O-:31])(=[O:30])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29].[Ba+2:11].[C:12]([O-:31])(=[O:30])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29].[C:32](=[O:9])([O-:34])[O-:33]