Carbon Dioxide → HCID 86746142, compound

HRID 440375Notes

Reaction equation

HRID 440375 reaction equation
C([OH:9])CCCCCCC.[O-2].[Ba+2:11].[C:12]([OH:31])(=[O:30])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29].[C:32](=[O:34])=[O:33]>O>[C:12]([O-:31])(=[O:30])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29].[Ba+2:11].[C:12]([O-:31])(=[O:30])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29].[C:32](=[O:9])([O-:34])[O-:33]

Participants

6

Reactant 4

HCID 280Carbon DioxideHCID 9571-OctanolHCID 445639Oleic AcidHCID 9855530Barium Oxide Nanoparticle Dispersion

Product 1

HCID 86746142HCID 86746142, compoundYield 21%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Conditions

Temperature
190 °C

Procedure

To a mixture of 50 g of octanol and 150 g of process oil (PUREXX12 : Esso Petroleum) was added 122 g of barium oxide gradually to disperse it, 24 g of water and 117 g of oleic acid were added, the mixture was stirred for 30 minutes, and carbon dioxide (20 L/hour) was blown thereinto at 130° C. for 3 hours to progress reaction. The mixture was gradually heated to 190° C. to continue reaction while water was distilled off, and then filtered to give a brown solution of an overbased barium oleate-carbonate complex (Ba=21%; metal ratio=3.4) (this product is designated S-2).

Workup

  1. additionwere added
  2. waitat 130° C. for 3 hours to progress
  3. customreaction
  4. distillationwas distilled off
  5. filtrationfiltered

Sources & evidence

ORD record
ord-575d17ef3706487d8dcb4ba1ad6996d8
Source dataset
uspto-grants-1996_05
Patent number
US05519076

Reaction notes

Loading…