tert-Butyl 4'-(bromomethyl)biphenyl-2-carboxylate → HCID 67732935, compound

HRID 440850Notes

Reaction equation

HRID 440850 reaction equation
[CH2:1]([C:4]1[NH:8][C:7]2[CH:9]=[C:10]([N:14]3[C:18](=[O:19])[C:17]4=[CH:20][CH:21]=[CH:22][CH:23]=[C:16]4[C:15]3=[O:24])[CH:11]=[C:12]([CH3:13])[C:6]=2[N:5]=1)[CH2:2][CH3:3].Br[CH2:26][C:27]1[CH:32]=[CH:31][C:30]([C:33]2[C:34]([C:39]([O:41]C(C)(C)C)=[O:40])=[CH:35][CH:36]=[CH:37][CH:38]=2)=[CH:29][CH:28]=1>>[C:12]([C:35]1[CH:36]=[CH:37][CH:38]=[C:33]([C:30]2[CH:29]=[CH:28][C:27]([CH2:26][N:8]3[C:7]4[CH:9]=[C:10]([N:14]5[C:15](=[O:24])[C:16]6=[CH:23][CH:22]=[CH:21][CH:20]=[C:17]6[C:18]5=[O:19])[CH:11]=[C:12]([CH3:13])[C:6]=4[N:5]=[C:4]3[CH2:1][CH2:2][CH3:3])=[CH:32][CH:31]=2)[C:34]=1[C:39]([OH:41])=[O:40])([CH3:13])([CH3:6])[CH3:11]

Participants

3

Reactant 2

HCID 9906257tert-Butyl 4'-(bromomethyl)biphenyl-2-carboxylateHCID 22075634HCID 22075634, compound

Product 1

HCID 67732935HCID 67732935, compound

Procedure

Prepared analogously to Example 1a from 2-n-propyl-4-methyl-6-phthalimido-1H-benzimidazole and tert.butyl 4'-bromomethyl-biphenyl-2-carboxylate.

Sources & evidence

ORD record
ord-293a7a7c114a40e687a054ea6db85e85
Source dataset
uspto-grants-1996_05
Patent number
US05521177

Reaction notes

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