HCID 21420833, compound → HCID 21420818, compound

HRID 441367Notes

Reaction equation

HRID 441367 reaction equation
[N+:1]([C:4]1[CH:11]=[C:10]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23])[CH:9]=[CH:8][C:5]=1[NH:6][CH3:7])([O-])=O>C(O)C.[Pd]>[NH2:1][C:4]1[CH:11]=[C:10]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23])[CH:9]=[CH:8][C:5]=1[NH:6][CH3:7]

Participants

4

Reactant 1

HCID 21420833HCID 21420833, compound

Product 1

HCID 21420818HCID 21420818, compoundYield 100%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

A solution of 2-nitro-4-dodecyl-N-methylaniline (32 g) in ethanol (250 ml) was hydrogenated using 5% palladium on charcoal (3 g) as catalyst. The mixture was filtered and the filtrate evaporated to dryness to give 29 g of 2-amino-4-dodecyl-N-methylaniline as a dark grey waxy solid.

Workup

  1. filtrationThe mixture was filtered
  2. customthe filtrate evaporated to dryness

Sources & evidence

ORD record
ord-3a740a2e9d2b4a57b9f183b125f3c3f7
Source dataset
uspto-grants-1977_08
Patent number
US04039612

Reaction notes

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