2-(Bromomethyl)-6-methoxyphenol → HCID 21417717, compound
Reaction equation
ON=[C:3]([C:5]1[C:14]2[C:9](=[CH:10][C:11]([OH:17])=[C:12]([O:15][CH3:16])[CH:13]=2)[CH:8]=[CH:7][N:6]=1)[CH3:4].[OH:18][C:19]1[C:26]([O:27][CH3:28])=[CH:25][CH:24]=[CH:23][C:20]=1[CH2:21][Br:22]>>[Br-:22].[OH:17][C:11]1[C:12]([O:15][CH3:16])=[CH:13][C:14]2=[C:5]3[N+:6](=[CH:7][CH:8]=[C:9]2[CH:10]=1)[CH:21]=[C:20]1[C:19]([OH:18])=[C:26]([O:27][CH3:28])[CH:25]=[CH:24][C:23]1=[C:3]3[CH3:4]Participants
3
Procedure
The procedure of Example 1 is repeated except that 1-(1-hydroxyiminoethyl)-6-hydroxy-7-methoxyisoquinoline and 2-hydroxy-3-methoxybenzyl bromide are used as the starting materials. m.p. 211°-217° C. (with decomposition).
Sources & evidence
- ORD record
- ord-8eb6aa754cd74d53bc9a5be75cb8dd12
- Source dataset
- uspto-grants-1977_08
- Patent number
- US04042592
Reaction notes
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