Vanadium tetrakis(dimethylamide) → HCID 178448251, compound

HRID 441781Notes

Reaction equation

HRID 441781 reaction equation
[CH3:1][N-:2][CH3:3].[CH3:4][N-:5][CH3:6].C[N-]C.C[N-]C.[V+4:13].[CH2:14]([Li])[CH2:15][CH2:16][CH3:17]>CCCCCC>[CH3:1][N-:2][CH3:3].[CH3:4][N-:5][CH3:6].[CH2:14]([V+2:13][CH2:14][CH2:15][CH2:16][CH3:17])[CH2:15][CH2:16][CH3:17]

Participants

4

Reactant 2

HCID 6097003Vanadium tetrakis(dimethylamide)HCID 178418339Butyllithium

Product 1

HCID 178448251HCID 178448251, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent2×

Procedure

To a dark-green solution of 0.048 g (0.21 mmol) of vanadium tetrakis(dimethylamide) in hexane was added from a syringe 0.26 ml of a 1.6 M solution of butyllithium (0.21 mmol) in hexane. Lithium dimethylamide precipitated rapidly. The total volume of liquid in the mixture was about 6 ml. After 15 minutes the mixture was filtered to give a clear green solution of dibutylvanadium bis(dimethylamide) in hexane.

Workup

  1. customLithium dimethylamide precipitated rapidly
  2. filtrationAfter 15 minutes the mixture was filtered

Sources & evidence

ORD record
ord-4d9e27ae8351466a831b5cc1873ac5d8
Source dataset
uspto-grants-1977_08
Patent number
US04042610

Reaction notes

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