HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-(Dimethylamino)Benzaldehyde → [4-(Dimethylamino)phenyl][4-(trimethylsilyl)phenyl]methanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-(Dimethylamino)Benzaldehyde | HCID 7479 | — |
| Reactant | (p-Chlorophenyl)trmethylsilane | HCID 66351 | — |
| Reactant | Magnesium | HCID 5462224 | — |
| Product | [4-(Dimethylamino)phenyl][4-(trimethylsilyl)phenyl]methanone | HCID 19964147 | — |
Reaction Steps
A Grignard reagent prepared from 0.2 mole of 4-trimethylsilylchlorobenzene and 0.2 mole of magnesium was reacted with 0.2 mole of 4-dimethylaminobenzaldehyde. The resulting reactant was subjected to oxidation by the Oppenauer method, to yield 4-dimethylamino-4'-trimethylsilyl benzophenone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04042613 |
| Source dataset | uspto-grants-1977_08 |
| ORD ID | ord-93e35cb85c0a413280d02cca1d27596a |
| Source note | uspto-grants-1977_08 |