HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Nitroanthraquinone → 1-dimethylaminoanthraquinone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Nitroanthraquinone | HCID 6704 | — |
| Reactant | Hexamethylphosphoramide | HCID 12679 | — |
| Solvent | Water | HCID 962 | — |
| Product | 1-dimethylaminoanthraquinone | HCID 2840206 | 92.4% |
Reaction Steps
25.3 parts of 1-nitroanthraquinone and 227 parts of hexamethylphosphoric triamide are heated in an agitator flask for 4 hours to 180° C and for 11/2 hours to 210° C. After it has been cooled, the reaction mixture is poured into 1000 parts of water. The precipitated product is collected by filtration, washed with water and dried, to yield 23.2 parts (=92.4% of theory) of 1-dimethylaminoanthraquinone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04044030 |
| Source dataset | uspto-grants-1977_08 |
| ORD ID | ord-d96da33a36b24121abc758dc5c619825 |
| Source note | uspto-grants-1977_08 |