HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoyl chloride → [Butane-1,4-diylbis(oxy-4,1-phenylene)]bis(phenylmethanone)
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoyl chloride | HCID 7412 | — |
| Reactant | Benzene, 1,1'-(1,4-butanediylbis(oxy))bis- | HCID 137944 | — |
| Reactant | Aluminum(III) Chloride | HCID 6451240 | — |
| Solvent | 1,2-Dichloroethane | HCID 11 | — |
| Product | [Butane-1,4-diylbis(oxy-4,1-phenylene)]bis(phenylmethanone) | HCID 20340700 | — |
Reaction Steps
1,4-Diphenoxy-n-butane (24.2 g) and benzoyl chloride (29 g) are reacted in 250 ml of 1,2-dichloroethane in the presence of aluminum chloride (28 g) for 4 hours at 60° to yield 18.3 g (41% of theory) of colorless crystals mp 163°-164°. Calculated for C30H26O4 : C, 79.98% H, 5.82%. Found: C, 80.16%; H, 5.98%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04044139 |
| Source dataset | uspto-grants-1977_08 |
| ORD ID | ord-6c6cf0d68a7f4b99add6ac44da1bb3c5 |
| Source note | uspto-grants-1977_08 |