HRID442268

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O=[N+]([O-])c1ccc(-c2c(F)c(F)c(F)c(F)c2F)cc1

HCID11254760

4-nitro-2',3',4',5',6'-pentafluorobiphenyl

C12H4F5NO2

HCID21416460

4-Fluoro-3-methoxy-4'-nitro-1,1'-biphenyl

C13H10FNO3

HCID21416463

未命名化合物

HCID21416465

未命名化合物

PRODUCTS

生成物

HCID15938617

未命名化合物

HCID16244341

未命名化合物

HCID21416474

未命名化合物

PROCEDURE

实验过程

When b 2', 3', 4', 5', 6'-pentafluoro-4-nitrobiphenyl, 2'-fluoro-4-nitrobiphenyl or 4'-fluoro-3'-methoxy-4-nitrobiphenyl obtained from Example 2 are used in place of 4'-fluoro-2'-methoxy-4-nitrobiphenyl in the above example, there is obtained 4-(pentafluorophenyl)-aniline, 4-(2'-fluorophenyl)-aniline or 4-(4'-fluoro-3'-methoxyphenyl)-aniline.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-05323558673d4890beee14aaab136974
来源数据集: uspto-grants-1977_08
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04044049
来源说明: uspto-grants-1977_08

反应 SMILES

[F:1][C:2]1[C:7]([F:8])=[C:6]([F:9])[C:5]([F:10])=[C:4]([F:11])[C:3]=1[C:12]1[CH:17]=[CH:16][C:15]([N+:18]([O-])=O)=[CH:14][CH:13]=1.[F:21][C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][C:23]=1[C:28]1[CH:33]=[CH:32][C:31]([N+:34]([O-])=O)=[CH:30][CH:29]=1.[F:37][C:38]1[CH:43]=[CH:42][C:41]([C:44]2[CH:49]=[CH:48][C:47]([N+:50]([O-])=O)=[CH:46][CH:45]=2)=[CH:40][C:39]=1[O:53][CH3:54].FC1C=CC(C2C=CC([N+]([O-])=O)=CC=2)=C(OC)C=1>>[F:1][C:2]1[C:3]([C:12]2[CH:17]=[CH:16][C:15]([NH2:18])=[CH:14][CH:13]=2)=[C:4]([F:11])[C:5]([F:10])=[C:6]([F:9])[C:7]=1[F:8].[F:21][C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][C:23]=1[C:28]1[CH:33]=[CH:32][C:31]([NH2:34])=[CH:30][CH:29]=1.[F:37][C:38]1[CH:43]=[CH:42][C:41]([C:44]2[CH:49]=[CH:48][C:47]([NH2:50])=[CH:46][CH:45]=2)=[CH:40][C:39]=1[O:53][CH3:54]