HuagongsheHuagongshe Chemistry Print Report · For research reference only
Bromine → HCID 21414997, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Bromine | HCID 24408 | — |
| Reactant | [(9,10-Methanoanthracen-9(10H)-yl)methyl]propanedioic acid | HCID 21414998 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Solvent | O-Xylene | HCID 7237 | — |
| Product | HCID 21414997 | HCID 21414997 | — |
Reaction Steps
α-Carboxy-β-(9,10-dihydro-9,10-methano-9-anthryl)-propionic acid was treated with bromine in ether, and the corresponding brominated compound was refluxed in xylene to give α-bromo-β-(9,10-dihydro-9,10-methano-9-anthryl)propionic acid. α-Bromo-β-(9,10-dihydro-9,10-methano-9-anthryl)-propionic acid was treated with thionyl chloride and then with N-benzyl-N-hydroxyethylamine to give α-bromo-β-(9,10-dihydro-9,10-methano-9anthryl)propionic acid N-benzyl-N-hydroxyethylamide, I.R., 3400, 3060, 3045, 2860, 1640, 1360, 1158, 1048, 1012, 698 cm-1.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04045560 |
| Source dataset | uspto-grants-1977_08 |
| ORD ID | ord-44f3adf3a8d1448a8677d5219aacf8c6 |
| Source note | uspto-grants-1977_08 |