HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl Ether → 4-[2-(9H-thioxanthen-9-yl)acetyl]benzonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl Ether | HCID 3283 | — |
| Reactant | ethyl 2-(4-cyanobenzoyl)-2-(9H-thioxanthen-9-yl)acetate | HCID 54398664 | — |
| Solvent | Dimethyl Sulfoxide | HCID 679 | — |
| Solvent | Water | HCID 962 | — |
| Product | 4-[2-(9H-thioxanthen-9-yl)acetyl]benzonitrile | HCID 70092535 | — |
Reaction Steps
A solution of ethyl 2-(4-cyanobenzoyl)-2-(9H-thioxanthen-9-yl)acetate (5 g, 12.0 mmol) in dimethylsulphoxide (50 ml) and water (0.45 ml) was reacted as described in Example 1 (iv) and the product was isolated in a similar manner except the extraction used diethyl ether to give 4-[2-(9H-thioxanthen-9-yl)acetyl]benzonitrile as a yellow oil which solidified on standing.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05891899 |
| Source dataset | uspto-grants-1999_04 |
| ORD ID | ord-e2e5368ffa294e1e9f25defbb7786050 |
| Source note | uspto-grants-1999_04 |