Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Butyl Acrylate | HCID 8846 | — |
| Reactant | (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 107526 | — |
| Reactant | Sodium Bicarbonate | HCID 516892 | — |
| Product | HCID 86636730 | HCID 86636730 | — |
Reaction Steps
Block Copolymerization To a 3 necked round bottom flask was added n-butyl acrylate (25 mL), glucose (0.119 grams), NaHCO3 (0.139 grams) and a polystyrene TEMPO terminated (2.068 g, Mn=6,000). This was purged with argon gas bubbling through the solution for 25 minutes. Then the flask was heated by immersion into a preheated oil bath of 145° C. After 5 hours, poly(styrene-b-n-butyl acrylate) was obtained with Mn=29,594, and PD=2.18 and conversion of 62 percent.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US05891971 |
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| Source dataset | uspto-grants-1999_04 |
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| ORD ID | ord-3e72536da84045309ee757bb0662df23 |
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| Source note | uspto-grants-1999_04 |
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