HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phenyl phenylglyoxylate → Phenyl 4-chlorobenzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phenyl phenylglyoxylate | HCID 13975017 | — |
| Reactant | 4-Chlorophenyl phenylglyoxylate | HCID 54442020 | — |
| Catalyst | Tetraphenylphosphonium Chloride | HCID 164911 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | Phenyl 4-chlorobenzoate | HCID 260766 | — |
Reaction Steps
The decarbonylation reaction of Example 79 was repeated except that phenyl phenylglyoxylate (PPG) was replaced with 4-chlorophenyl phenylglyoxylate (4-CPPG), and that the amounts of tetraphenylphosphonium chloride and chloroform were changed as set forth in Table 13. The results are set forth in Table 13.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05892091 |
| Source dataset | uspto-grants-1999_04 |
| ORD ID | ord-b4c01714edc043b29f69990524dc94d0 |
| Source note | uspto-grants-1999_04 |