HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 443771Generated: October 29, 2026
Methylamine → N-methyl-4-nitro-2-trichloromethylphenylsulfenamide
https://huagongshe.com/reaction/443771
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Methylamine | HCID 6329 | — |
| Reactant | 4-Nitro-2-trichloromethylbenzenesulfenyl chloride | HCID 12763555 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | N-methyl-4-nitro-2-trichloromethylphenylsulfenamide | HCID 23465359 | 85% |
Reaction Steps
At 0° C., 10 liters of methylamine is passed into a solution of 61.4 g of 4-nitro-2-trichloromethylbenzenesulfenyl chloride in 200 ml of diethyl ether. After the mixture has been stirred for 6 hours at 25° C., it is poured onto ice water, and the aqueous phase is separated and evaporated to dryness. There is obtained 51 g (85% of theory) of N-methyl-4-nitro-2-trichloromethylphenylsulfenamide as an oil (nD20 :1.6610).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04261924 |
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| Source dataset | uspto-grants-1981_04 |
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| ORD ID | ord-84de7db69b0b4b8cbdba3569c31b7cd5 |
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| Source note | uspto-grants-1981_04 |
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