HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetone → HCID 86737701, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetone | HCID 180 | — |
| Reactant | 2-Bromo-4'-methylacetophenone | HCID 69272 | — |
| Reactant | 4-NITROPHENOL SODIUM SALT DIHYDRATE | HCID 2735104 | — |
| Product | HCID 86737701 | HCID 86737701 | 78.9% |
Reaction Steps
4-Methylphenacyl chloride (XVI: X=Cl) (37.8 g, 0.224 mole) and sodium 4-nitrophenolate (XI) (38.6 g, 0.24 mole) were added to acetone (300 ml), and the mixture was heated under reflux for 10 hours. Thereafter, the reaction mixture was treated in the same manner as in Example 29 to obtain 47.9 g of 4-methyl-α-(4-nitrophenoxy)acetophenone (XII) (yield, 78.9%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04263219 |
| Source dataset | uspto-grants-1981_04 |
| ORD ID | ord-e154d898655b47cb8e2c2b9cfcd36a44 |
| Source note | uspto-grants-1981_04 |