HuagongsheHuagongshe Chemistry Print Report · For research reference only
tert-Butyl hydroperoxide → 2-Cyclopenten-1-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | tert-Butyl hydroperoxide | HCID 6410 | — |
| Reactant | Cyclopentene | HCID 8882 | — |
| Product | 2-Cyclopenten-1-one | HCID 13588 | 10% |
| Product | 2-Cyclopentene-1-ol | HCID 220164 | — |
Reaction Steps
East German Pat. No. 81650 issued on May 5, 1971 discloses the use of Rh(Pφ3)3Cl and a large amount of t-butyl hydroperoxide (with oxygen) for the oxidation of cyclopentene at 45° C. This reaction was slow giving 2-cyclopentenol in 7% yield along with 10% of 2-cyclopentenone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04263447 |
| Source dataset | uspto-grants-1981_04 |
| ORD ID | ord-34e37f845f534495a0551a57745f15b8 |
| Source note | uspto-grants-1981_04 |