Ethyl 3,3-dimethylacrylate → Ethyl 3-methyldecanoate

HRID 444335Notes

Reaction equation

C[CH:2]([CH2:6][CH2:7][CH2:8]CCCC)[CH2:3][CH2:4]O.C(Cl)(=O)CCCCC.[CH2:21]([O:23][C:24](=[O:29])[CH:25]=[C:26]([CH3:28])[CH3:27])[CH3:22]>>[CH2:21]([O:23][C:24](=[O:29])[CH2:25][CH:26]([CH3:28])[CH2:27][CH2:4][CH2:3][CH2:2][CH2:6][CH2:7][CH3:8])[CH3:22]

Participants

Reactant 3

HCID 12516Ethyl 3,3-dimethylacrylate

HCID 67340Hexanoyl chloride

HCID 150549973-Methyl-1-decanol

Product 1

HCID 560492Ethyl 3-methyldecanoate

Procedure

The starting compound 3-methyl-undecanol (b.p.0.5 :105° C.) is prepared, in the same way as that described in Example 1 for the preparation of 3-methyldecanol, from hexanoic acid chloride and dimethylacrylic acid ethyl ester.

Sources & evidence

ORD record: ord-74e715f2ec1043a4af1b0dadb0fce284
Source dataset: uspto-grants-1981_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04263459

Reaction notes

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