HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Hydroxymethyl-2,3,3-trimethyl-cyclohexa-1,5-diene → HCID 20569431, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Hydroxymethyl-2,3,3-trimethyl-cyclohexa-1,5-diene | HCID 20569433 | — |
| Catalyst | Nickel | HCID 935 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 20569431 | HCID 20569431 | 91.6% |
Reaction Steps
30.4 g of 1-hydroxymethyl-2,3,3-trimethyl-cyclohexa-1,5-diene were hydrogenated at 10°-12° in the presence of 1g of Raney-nickel in 300 ml of ethanol. 3.95 l of hydrogen were thus absorbed within 2.5 h. A filtration followed by evaporation and distillation gave 28.2 g of 1-hydroxymethyl-2,3,3-trimethyl-cyclohex-5-ene. nD =1.4862, d20 =0.9447
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04264467 |
| Source dataset | uspto-grants-1981_04 |
| ORD ID | ord-bb0e65c9d05b48c69f11a658e1f1b842 |
| Source note | uspto-grants-1981_04 |