HCID 86617060, compound → HCID 86617059, compound

HRID 446693Notes

Reaction equation

HRID 446693 reaction equation
[Cl:1][C:2]1[C:10]2[C:9]3[C:11]([Cl:20])=[C:12]([Cl:19])[C:13]([Cl:18])=[C:14]([N+:15]([O-])=O)[C:8]=3[O:7][C:6]=2[C:5]([N+:21]([O-])=O)=[C:4]([Cl:24])[C:3]=1[Cl:25]>C(O)C>[Cl:20][C:11]1[C:9]2[C:10]3[C:2]([Cl:1])=[C:3]([Cl:25])[C:4]([Cl:24])=[C:5]([NH2:21])[C:6]=3[O:7][C:8]=2[C:14]([NH2:15])=[C:13]([Cl:18])[C:12]=1[Cl:19]

Participants

3

Reactant 1

HCID 86617060HCID 86617060, compound

Product 1

HCID 86617059HCID 86617059, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The corresponding amine was prepared by reducing 1,2,3,7,8,9-hexachloro-4,6-dinitrodibenzofuran with 3.6 mmol of NaSH in 5 ml of ethanol. The resulting 1,2,3,7,8,9-hexachloro-4,6-diaminodibenzofuran was isolated by extracting with five times 30 ml of diethyl ether. The resulting solution was washed twice with 10 ml of water and dried over magnesium sulfate. Subsequently, the amine was removed from the desiccant and isolated again.

Sources & evidence

ORD record
ord-0bad3a87cad14ce483e7e74aa65920f3
Source dataset
uspto-grants-2013_07
Patent number
US08481327B2

Reaction notes

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