HuagongsheHuagongshe Chemistry Print Report · For research reference only
6,7-Methylenedioxyoxindole → 5H-[1,3]dioxolo[4,5-f]indole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 6,7-Methylenedioxyoxindole | HCID 21282011 | — |
| Reactant | 4,5-Methylenedioxyoxindole | HCID 21282023 | — |
| Reactant | 5,6-Methylenedioxyoxindole | HCID 21282101 | — |
| Reactant | Methyl 2-(6-nitrobenzo[d][1,3]dioxol-5-yl)acetate | HCID 21282102 | — |
| Reactant | Methyl 2-nitromethylenedioxyphenylacetate | HCID 70406732 | — |
| Product | 5H-[1,3]dioxolo[4,5-f]indole | HCID 260797 | — |
Reaction Steps
5,6-Methylenedioxyoxindole can be prepared via the reduction of methyl 2-nitro-4,5-methylenedioxyphenylacetate according to the procedure of McEvoy et al., J. Org. Chem., 38, 3350 (1973). By a similar procedure, starting with the appropriate methyl 2-nitromethylenedioxyphenylacetate, 4,5-methylenedioxyoxindole and 6,7-methylenedioxyoxindole are prepared.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04725616 |
| Source dataset | uspto-grants-1988_02 |
| ORD ID | ord-3ed5c8b0016f4432bfed93da605fb3ce |
| Source note | uspto-grants-1988_02 |