Nitric Acid → HCID 86615902, compound

HRID 448004Notes

Reaction equation

HRID 448004 reaction equation
[C:1]1([CH:7]([CH2:13][S:14]([OH:17])(=[O:16])=[O:15])[CH2:8][S:9]([OH:12])(=[O:11])=[O:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.OS(O)(=O)=O.[N+:23]([O-])([OH:25])=[O:24]>>[N+:23]([C:4]1[CH:5]=[CH:6][C:1]([CH:7]([CH2:13][S:14]([OH:17])(=[O:16])=[O:15])[CH2:8][S:9]([OH:12])(=[O:11])=[O:10])=[CH:2][CH:3]=1)([O-:25])=[O:24]

Participants

4

Reactant 3

HCID 944Nitric AcidHCID 1118Sulfuric AcidHCID 86615900HCID 86615900, compound

Product 1

HCID 86615902HCID 86615902, compound

Procedure

2-Phenyl-propane-1,3-disulfonic acid (as prepared in the previous step) is treated with concentrated H2SO4 and fuming HNO3 according to the procedure of Example 2, step (a) to afford the title compound.

Sources & evidence

ORD record
ord-68ea3655acd943e5af68c1964d1d8678
Source dataset
uspto-grants-2013_07
Patent number
US08481564B2

Reaction notes

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