HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,3-Dichloro-5,6-dicyano-1,4-benzoquinone → HCID 66815199, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone | HCID 6775 | — |
| Reactant | Sodium Acetate | HCID 517045 | — |
| Reactant | 4-Cyanophenylhydrazine Hydrochloride | HCID 16212962 | — |
| Product | HCID 66815199 | HCID 66815199 | 93.3% |
Reaction Steps
4-cyanophenylhydrazine hydrochloride (1.36 g; 8.0 mmol), sodium acetate (656 mg; 8.0 mmol); stage B: DDQ (545 mg; 2.40 mmol); stage C: chromatography on silica gel (from 9/1 to 7/3 cyclohexane/EtOAc) allows isolation of the expected compound (517 mg; 2.24 mmol; yield=56%) in the form of a beige-colored solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08481586B2 |
| Source dataset | uspto-grants-2013_07 |
| ORD ID | ord-c18b58915db645bd99224383a7621419 |
| Source note | uspto-grants-2013_07 |