4-Methyl-m-anisic acid → HCID 67366354, compound

HRID 448182Notes

Reaction equation

HRID 448182 reaction equation
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:10]=[CH:11][C:12]=1[CH3:13])[C:6]([O:8][CH3:9])=[O:7].COC1C=C(C=CC=1C)C(O)=O.ClC1C=C(C=CC=1C[C:38]([C:40]1[CH:45]=[CH:44][C:43]([OH:46])=[CH:42][C:41]=1[OH:47])=[O:39])C(OC)=O>>[OH:47][C:41]1[CH:42]=[C:43]([OH:46])[CH:44]=[CH:45][C:40]=1[C:38](=[O:39])[CH2:13][C:12]1[CH:11]=[CH:10][C:5]([C:6]([O:8][CH3:9])=[O:7])=[CH:4][C:3]=1[O:2][CH3:1]

Participants

4

Reactant 3

HCID 815794-Methyl-m-anisic acidHCID 591123Benzoic acid, 3-methoxy-4-methyl-, methyl esterHCID 67365584Benzoic acid, 3-chloro-4-[2-(2,4-dihydroxyphenyl)-2-oxoethyl]-, methyl ester

Product 1

HCID 67366354HCID 67366354, compound

Procedure

Synthesis of methyl 3-methoxy-4-methylbenzoate, starting with 3-methoxy-4-methylbenzoic acid (see step 1 of Intermediate F). MS (ESI): m/z 181.1 [M+1]+.

Sources & evidence

ORD record
ord-c073803a827842238fe0e0824ae306fc
Source dataset
uspto-grants-2013_07
Patent number
US08481590B2

Reaction notes

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