化工社化工社 化学情報印刷レポート · 研究参考用
1,1,1,3-Tetrachloropropane → 1,1,3-Trichloropropene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,1,1,3-Tetrachloropropane | HCID 14056 | — |
| 反応物 | Chlorine | HCID 24526 | — |
| 生成物 | 1,1,3-Trichloropropene | HCID 17378 | — |
| 生成物 | 1,1,2,3-Tetrachloro-1-propene | HCID 25281 | — |
| 生成物 | 1,1,1,2,3-Pentachloropropane | HCID 13454491 | — |
反応手順
Chlorine conversion was 99%; 1,1,1,3-tetrachloropropane conversion was 99%. The yields of 1,1,3-trichloropropene, 1,1,1,2,3-pentachloropropane, and 1,1,2,3-tetrachloropropene on 1,1,1,3-tetrachloropropane fed were 2.0, 85, and 5.8 percent, respectively. The total yield of four prominent high-boiling byproducts was 3.3 wt % in the reactor effluent. These byproducts are believed to be hexachloropropane, two pentachlorohexene isomers, and hexachlorohexadiene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08487146B2 |
| 出典データセット | uspto-grants-2013_07 |
| ORD ID | ord-696ec0801ad24ed1aa1c961231866306 |
| 出典メモ | uspto-grants-2013_07 |