HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-(Methylthio)phenylboronic acid → Methyl 3-[4-(methylthio)phenyl]benzo[b]thiophene-5-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-(Methylthio)phenylboronic acid | HCID 2733959 | — |
| Reactant | HCID 59509366 | HCID 59509366 | — |
| Product | Methyl 3-[4-(methylthio)phenyl]benzo[b]thiophene-5-carboxylate | HCID 44482296 | 76% |
Reaction Steps
In the same manner as in Reference Example 19 and using methyl 3-bromo-1-benzothiophene-5-carboxylate instead of methyl 3-iodoimidazo[1,2-a]pyridine-6-carboxylate and [4-(methylthio)phenyl]boronic acid instead of (4-methoxyphenyl)boronic acid, the title compound (yield 76%) was obtained as colorless crystals.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08492378B2 |
| Source dataset | uspto-grants-2013_07 |
| ORD ID | ord-7c64d3489f4c4949b043ed88178e9bce |
| Source note | uspto-grants-2013_07 |