4-(Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline → HCID 57666517, compound

HRID 456013Notes

Reaction equation

HRID 456013 reaction equation
[CH3:1][C:2]1([CH3:27])[CH2:7][C:6](OS(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)(=O)=O)=[CH:5][C:4]([CH3:26])([CH3:25])[S:3]1.CC1(C)C(C)(C)OB([C:36]2[CH:41]=[CH:40][C:39]([NH2:42])=[CH:38][CH:37]=2)O1>>[CH3:27][C:2]1([CH3:1])[CH2:7][C:6]([C:36]2[CH:41]=[CH:40][C:39]([NH2:42])=[CH:38][CH:37]=2)=[CH:5][C:4]([CH3:25])([CH3:26])[S:3]1

Participants

3

Reactant 2

HCID 27346204-(Tetramethyl-1,3,2-dioxaborolan-2-yl)anilineHCID 57666561HCID 57666561, compound

Product 1

HCID 57666517HCID 57666517, compound

Procedure

The title compound was prepared from 1,1,2,2,3,3,4,4,4-nonafluoro-butane-1-sulfonic acid 2,2,6,6-tetramethyl-3,6-dihydro-2H-thiopyran-4-yl ester (as prepared in Example 21, step (a)) and 4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenylamine according to the procedure of Example 15, step (c). Mass spectrum (ESI, m/z): Calcd. for C15H21NS, 248.1 (M+H), found 248.2.

Sources & evidence

ORD record
ord-0b5ba25f63ce438b8aeaedad15498aa5
Source dataset
uspto-grants-2013_07
Patent number
US08497376B2

Reaction notes

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