HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzenamine, 4-methyl-N-(4-nitrophenyl)- → N1-(p-Tolyl)benzene-1,4-diamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzenamine, 4-methyl-N-(4-nitrophenyl)- | HCID 94859 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | N1-(p-Tolyl)benzene-1,4-diamine | HCID 4764072 | 85% |
Reaction Steps
Reduction of the nitro function of N-(4-methylphenyl)-4-nitroaniline (Indian J. Chem. (1981) 20B, 611–613) is carried out in the presence of Pd/C in ethanol, under the conditions described for intermediate 2.2. A grey solid is obtained with a yield of 85%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07186752B2 |
| Source dataset | uspto-grants-2007_03 |
| ORD ID | ord-157ce11635fa45489be0cdd913c77b31 |
| Source note | uspto-grants-2007_03 |