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HRID457518

反应详情

EQUATION

反应方程式

HRID 457518 的结构方程式

REACTANTS

反应物

1
结构：CCc1ccc(Cc2c(O[C@@H]3O[C@H](CO)[C@@H](O)[C@H](O)[C@H]3O)nn(CCOCc3ccccc3)c2C)cc1
HCID69133733

未命名化合物

PRODUCTS

生成物

1
结构：CCc1ccc(Cc2c(O[C@@H]3O[C@H](CO)[C@@H](O)[C@H](O)[C@H]3O)nn(CCO)c2C)cc1
HCID69134411

未命名化合物

收率 111.2%

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[C].[Pd]
催化剂HCID178418390

未命名化合物

结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

To a solution of 1-(2-benzyloxyethyl)-4-[(4-ethylphenyl)methyl]-3-(β-D-glucopyranosyloxy)-5-methyl-1H-pyrazole (0.012 g) in ethanol (2 mL) was added a catalytic amount of 10% palladium-carbon powder, and the mixture was stirred at room temperature under a hydrogen atmosphere for 30 minutes. Insoluble materials were removed by filtration, and the solvent was removed under reduced pressure to give 4-[(4-ethylphenyl)methyl]-3-(β-D-glucopyranosyloxy)-1-(2-hydroxyethyl)-5-methyl-1H-pyrazole (0.011 g).

WORKUP

后处理

  1. customInsoluble materials were removed by filtration
  2. customthe solvent was removed under reduced pressure