Dimethyl malonate → Dimethyl 4-[2-(2-naphthoxy)ethoxy]benzylidenemalonate

Beteiligte Stoffe

Reaktionsschritte

To a solution of 4-[2-(2-naphthoxy)ethoxy]benzaldehyde (1.24 g, 4.26 mmol) and dimethyl malonate (1.69 g, 12.78 mmol) in toluene (30 ml) is added a catalytic quantity of piperidinium acetate. Then the mixture is refluxed in a Dean-Stark trap for 8 hours. After cooled to room temperature, the solution was concentrated under a vacuum to give title compound (1.45 g, 84%).

Herkunft & Nachweise