化工社化工社 化学情報印刷レポート · 研究参考用
(3-Bromo-4-chlorophenyl)methanol → 3-Bromo-4-chlorobenzaldehyde
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | (3-Bromo-4-chlorophenyl)methanol | HCID 50998689 | — |
| 触媒 | Manganese dioxide | HCID 14801 | — |
| 溶媒 | Acetone | HCID 180 | — |
| 生成物 | 3-Bromo-4-chlorobenzaldehyde | HCID 14049809 | 62.4% |
反応手順
A solution of 3-bromo-4-chlorobenzyl alcohol (3.24 g, 14.6 mmol) in acetone (100 mL) was treated with MnO2 (16.2 g, 73 mmol) and the mixture stirred for 3 days then filtered over diatomaceous earth. The filtrate was concentrated under reduced pressure to afford 2.0 g of title compound.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07196102B2 |
| 出典データセット | uspto-grants-2007_03 |
| ORD ID | ord-294ab56614fc44a6a54189571da03d8a |
| 出典メモ | uspto-grants-2007_03 |