(S)-(+)-Glycidyl-4-nitrobenzoate → HCID 60077932, compound

HRID 460584Notes

Reaction equation

HRID 460584 reaction equation
[OH:1][C:2]1[C:10]2[CH:9]=[C:8]([C:11]3[O:12][C:13]([C:16]([F:19])([F:18])[F:17])=[N:14][N:15]=3)[O:7][C:6]=2[CH:5]=[CH:4][CH:3]=1.S(C1C=CC([N+]([O-])=O)=CC=1)(O[CH2:24][C@H:25]1[O:27][CH2:26]1)(=O)=O>>[CH2:24]([O:1][C:2]1[C:10]2[CH:9]=[C:8]([C:11]3[O:12][C:13]([C:16]([F:19])([F:18])[F:17])=[N:14][N:15]=3)[O:7][C:6]=2[CH:5]=[CH:4][CH:3]=1)[C@H:25]1[O:27][CH2:26]1

Participants

3

Reactant 2

HCID 10868995(S)-(+)-Glycidyl-4-nitrobenzoateHCID 135794309HCID 135794309, compound

Product 1

HCID 60077932HCID 60077932, compoundYield 27.6%

Procedure

By the reactions in the same manner as in Starting Material Synthesis Example 1 using 2-(4-hydroxybenzo(b)furan-2-yl)-5-trifluoromethyl-1,3,4-oxadiazole (3.3 g) and (S)-glycidyl nosylate (3.7 g), the title compound (1.1 g) was obtained as white crystals.

Sources & evidence

ORD record
ord-41c0f20545a64708bd04591c6b42aeef
Source dataset
uspto-grants-2007_03
Patent number
US07196199B2

Reaction notes

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