N,N'-Dimethylthiourea → HCID 21394740, compound

HRID 460835Notes

Reaction equation

HRID 460835 reaction equation
[CH2:1]([NH:8][S:9]([C:12]1[C:13]([Cl:23])=[CH:14][C:15]([Cl:22])=[C:16]([C:18](=[O:21])[CH2:19][Br:20])[CH:17]=1)(=[O:11])=[O:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:24][NH:25][C:26]([NH:28][CH3:29])=[S:27]>>[BrH:20].[CH2:1]([NH:8][S:9]([C:12]1[C:13]([Cl:23])=[CH:14][C:15]([Cl:22])=[C:16]([C:18]2([OH:21])[CH2:19][S:27][C:26](=[N:25][CH3:24])[N:28]2[CH3:29])[CH:17]=1)(=[O:11])=[O:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 2723631N,N'-DimethylthioureaHCID 21394749HCID 21394749, compound

Product 1

HCID 21394740HCID 21394740, compound

Procedure

2,2 g of 5'-benzylsulfamoyl-2-bromo-2',4'dichloro-acetophenone were reacted in a manner analogous to the method described in Example 10 with 0.5 g of 1,3-dimethyl-thiourea. M.p. 201° C (decomposition).

Sources & evidence

ORD record
ord-78e4182d1927427fb4cd9137eda2c3c6
Source dataset
uspto-grants-1977_12
Patent number
US04061647

Reaction notes

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