HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetonitrile → (2,4-Dimethyl-3-thenyl)triphenylphosphonium bromide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetonitrile | HCID 6342 | — |
| Reactant | Phosphine, triphenyl-, hydrobromide | HCID 517696 | — |
| Reactant | (2,4-Dimethylthiophen-3-yl)methanol | HCID 12875266 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | (2,4-Dimethyl-3-thenyl)triphenylphosphonium bromide | HCID 20285733 | — |
Reaction Steps
4.4 G of 2,4-dimethyl-3-hydroxymethylthiophene and 10.7 g. of triphenylphosphonium bromide were dissolved in 40 ml. of acetonitrile and stirred at 40° C. for 1 hour. The resulting solution was cooled and 150 ml. of ethyl ether was added. The white precipitate which formed was filterd and washed with cold acetone to yield (2,4-dimethyl-3-thenyl)triphenylphosphonium bromide, m.p. 262°-265° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04061656 |
| Source dataset | uspto-grants-1977_12 |
| ORD ID | ord-de5fea09e3db4610b1976a602b678f2c |
| Source note | uspto-grants-1977_12 |