(3-Chloroallyl)benzene → HCID 86735258, compound

HRID 461406Notes

Reaction equation

HRID 461406 reaction equation
[Cl:1][CH:2]=[CH:3][CH2:4][C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][CH:10]=1.C1C(C(OO)=[O:18])=CC=CC=1>C(Cl)(Cl)Cl>[Cl:1][CH:2]=[CH:3][CH2:4][C:5]1[CH:10]2[O:18][CH:9]2[CH:8]=[CH:7][CH:6]=1

Participants

4

Reactant 2

HCID 138711(3-Chloroallyl)benzeneHCID 523077Perbenzoic acid

Product 1

HCID 86735258HCID 86735258, compoundYield 33%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

(a) To 6.1 g of m-chloroallylbenzene was added 85 ml of chloroform solution containing perbenzoic acid and the mixture was allowed to stand at room temperature overnight. This solution was washed with sodium hydroxide solution, 20% Mohr's salt solution and then water, and dried over anhydrous sodium sulfate. The solvent was evaporated to obtain the residue, which was distilled under reduced pressure to give 2.2 g (yield 33%) of m-chloroallylbenzene oxide having a boiling point of 117° C/7 mmHg.

Workup

  1. washThis solution was washed with sodium hydroxide solution, 20% Mohr's salt solution
  2. dry with materialwater, and dried over anhydrous sodium sulfate
  3. customThe solvent was evaporated
  4. customto obtain the residue, which
  5. distillationwas distilled under reduced pressure

Sources & evidence

ORD record
ord-d1e595a6ebd34d55941ba2e2dd1178dd
Source dataset
uspto-grants-1977_12
Patent number
US04062862

Reaction notes

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