Benzoyl Peroxide → HCID 86735259, compound

HRID 461407Notes

Reaction equation

HRID 461407 reaction equation
[F:1][CH:2]=[CH:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.C1C(C(OO)=[O:18])=CC=CC=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)Cl>[F:1][CH:2]=[CH:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]2[O:18][CH:7]2[CH:6]=1

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 523077Perbenzoic acidHCID 53811129HCID 53811129, compound

Product 1

HCID 86735259HCID 86735259, compoundYield 52%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

7 g of p-fluoroallylbenzene was added to 800 ml of chloroform solution containing perbenzoic acid prepared from 46 g of benzoyl peroxide and the mixture was allowed to stand at about 5° C for 5 days. The resulting mixture was washed with sodium hydroxide solution, water, Mohr's salt solution, then water, and dried over anhydrous sodium sulfate. The solvent was evaporated and the residue was distilled under reduced pressure to give 4.1 g (yield 52%) of p-fluoroallylbenzene oxide as colorless liquid.

Workup

  1. washThe resulting mixture was washed with sodium hydroxide solution, water, Mohr's salt solution
  2. dry with materialwater, and dried over anhydrous sodium sulfate
  3. customThe solvent was evaporated
  4. distillationthe residue was distilled under reduced pressure

Sources & evidence

ORD record
ord-70e33044fcdb4d85ba7bb54a5f0519b8
Source dataset
uspto-grants-1977_12
Patent number
US04062862

Reaction notes

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