4-Phenyl-2-butene → HCID 86735263, compound

HRID 461409Notes

Reaction equation

HRID 461409 reaction equation
[CH3:1][CH:2]=[CH:3][CH2:4][C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][CH:10]=1.C1C(C(OO)=[O:18])=CC=CC=1>C(Cl)(Cl)Cl>[CH3:1][CH:2]=[CH:3][CH2:4][C:5]1[CH:10]2[O:18][CH:9]2[CH:8]=[CH:7][CH:6]=1

Participants

4

Reactant 2

HCID 152634-Phenyl-2-buteneHCID 523077Perbenzoic acid

Product 1

HCID 86735263HCID 86735263, compoundYield 19%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

To 5.3 g of m-methylallylbenzene was added 85 ml of chloroform solution containing perbenzoic acid and the mixture was allowed to stand at room temperature overnight. The resulting solution was washed with sodium hydroxide solution, Mohr's salt solution and then water, and dried over anhydrous sodium sulfate. The solvent was evaporated to obtain the residue, which was distilled under reduced pressure to give 1.1 g (yield 19%) of m-methylallylbenzene oxide having a boiling point of 90° C/7 mmHg.

Workup

  1. washThe resulting solution was washed with sodium hydroxide solution, Mohr's salt solution
  2. dry with materialwater, and dried over anhydrous sodium sulfate
  3. customThe solvent was evaporated
  4. customto obtain the residue, which
  5. distillationwas distilled under reduced pressure

Sources & evidence

ORD record
ord-004dbd67dbe14e27a54145f8fbc7017f
Source dataset
uspto-grants-1977_12
Patent number
US04062862

Reaction notes

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