Benzoyl Peroxide → HCID 86735264, compound

HRID 461410Notes

Reaction equation

HRID 461410 reaction equation
[CH:1]1[C:6]([C:7](OO)=O)=[CH:5][CH:4]=[CH:3][CH:2]=1.C(OOC(=O)C1C=CC=CC=1)(=[O:18])C1C=CC=CC=1.[CH2:29]([C:32]1C=CC(C)=CC=1)[CH:30]=C>C(Cl)(Cl)Cl>[CH3:30][CH:29]=[CH:32][CH2:7][C:6]1[CH:5]=[CH:4][CH:3]2[O:18][CH:2]2[CH:1]=1

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 76851Benzene, 1-methyl-4-(2-propenyl)-HCID 523077Perbenzoic acid

Product 1

HCID 86735264HCID 86735264, compoundYield 47.5%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

To chloroform solution containing perbenzoic acid prepared from 36.6 g of benzoyl peroxide was added, with ice-cooling, 6.6 g of p-allyltoluene dissolved in 20 ml of chloroform. The resulting mixture was allowed to stand at 5° C for 4 days and washed with 10% sodium hydroxide solution, water, Mohr's salt solution and then water, and dried over anhydrous sodium sulfate. The solvent was evaporated to obtain the residue, which was distilled under reduced pressure to give 35.3 g (yield 47.5%) of p-methylallylbenzene oxide as colourless liquid having a boiling point of 92° C/7 mmHg.

Workup

  1. additionwas added, with ice-
  2. temperaturecooling
  3. washwashed with 10% sodium hydroxide solution, water, Mohr's salt solution
  4. dry with materialwater, and dried over anhydrous sodium sulfate
  5. customThe solvent was evaporated
  6. customto obtain the residue, which
  7. distillationwas distilled under reduced pressure

Sources & evidence

ORD record
ord-65d1b1684369464d8917695f70e7280c
Source dataset
uspto-grants-1977_12
Patent number
US04062862

Reaction notes

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