Benzoyl Peroxide → HCID 86735267, compound

HRID 461412Notes

Reaction equation

HRID 461412 reaction equation
C1C(C(OO)=[O:8])=CC=CC=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.[CH2:29]([CH2:32][CH2:33][CH2:34][C:35]1[CH:40]=[CH:39][CH:38]=[CH:37][CH:36]=1)[CH:30]=[CH2:31]>C(Cl)(Cl)Cl>[CH2:29]([CH:32]=[CH:33][CH2:34][C:35]1[CH:36]=[CH:37][CH:38]2[O:8][CH:39]2[CH:40]=1)[CH2:30][CH3:31]

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 519188hex-5-enylbenzeneHCID 523077Perbenzoic acid

Product 1

HCID 86735267HCID 86735267, compoundYield 76%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

To perbenzoic acid in chloroform prepared from 65.5 g of benzoylperoxide was added 1.45 g of p-allylpropylbenzene and the mixture was allowed to stand at 5° C for 6 days. After the completion of the reaction, the mixture was washed with 2% sodium hydroxide solution, water, Mohr's salt solution, then water, and dried over anhydrous sodium sulfate. The solvent was evaporated to obtain the residue, which was distilled under reduced pressure to give 12.1 g (yield 76%) of p-n-propylallylbenzene oxide as colourless liquid.

Workup

  1. customAfter the completion of the reaction
  2. washthe mixture was washed with 2% sodium hydroxide solution, water, Mohr's salt solution
  3. dry with materialwater, and dried over anhydrous sodium sulfate
  4. customThe solvent was evaporated
  5. customto obtain the residue, which
  6. distillationwas distilled under reduced pressure

Sources & evidence

ORD record
ord-5a7c4a84a60c48728305ae320bc3d928
Source dataset
uspto-grants-1977_12
Patent number
US04062862

Reaction notes

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