Benzoyl Peroxide → HCID 21393576, compound

HRID 461416Notes

Reaction equation

HRID 461416 reaction equation
C1[C:6]([C:7](OO)=[O:8])=CC=CC=1.C(OOC(=O)C1C=CC=CC=1)(=[O:18])C1C=CC=CC=1.CO[CH:31]=[CH:32][CH2:33][C:34]1[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=1>C(Cl)(Cl)Cl>[CH2:7]([O:8][C:32](=[CH2:31])[CH2:33][C:34]12[O:18][CH:39]1[CH:38]=[CH:37][CH:36]=[CH:35]2)[CH3:6]

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 523077Perbenzoic acidHCID 13346382HCID 13346382, compound

Product 1

HCID 21393576HCID 21393576, compoundYield 41%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

To the chloroform solution containing perbenzoic acid prepared from 29 g of benzoyl peroxide was added 6.5 g of o-methoxyallylbenzene dissolved in 20 ml of chloroform, and the mixture was allowed to stand at 0° - 5° C for 3 days. The resulting mixture was washed with 10% sodium hydroxide solution, Mohr's salt solution and then water, and dried over anhydrous sodium sulfate. The solvent was evaporated to obtain the residue, which was distilled under reduced pressure to give 2.9 g (yield 41%) of 2-ethoxyallylbenzene oxide as pale yellow clear liquid having a boiling point of 120° - 121° C/9 mmHg.

Workup

  1. washThe resulting mixture was washed with 10% sodium hydroxide solution, Mohr's salt solution
  2. dry with materialwater, and dried over anhydrous sodium sulfate
  3. customThe solvent was evaporated
  4. customto obtain the residue, which
  5. distillationwas distilled under reduced pressure

Sources & evidence

ORD record
ord-429a2ed1cb344ca0bef3e61934f9917c
Source dataset
uspto-grants-1977_12
Patent number
US04062862

Reaction notes

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