Benzoyl Peroxide → HCID 86735270, compound

HRID 461417Notes

Reaction equation

HRID 461417 reaction equation
[F:1][C:2]([CH:5]=[CH:6][CH2:7][C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1)([F:4])[F:3].C1C(C(OO)=[O:21])=CC=CC=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)Cl>[F:1][C:2]([CH:5]=[CH:6][CH2:7][C:8]1[CH:13]2[O:21][CH:12]2[CH:11]=[CH:10][CH:9]=1)([F:3])[F:4]

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 523077Perbenzoic acidHCID 12591112HCID 12591112, compound

Product 1

HCID 86735270HCID 86735270, compoundYield 77%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

7.4 g of m-trifluoromethylallylbenzene was added to chloroform solution containing perbenzoic acid prepared from 29.3 g of benzoyl peroxide and the mixture was allowed to stand at about 5° C for 7 days. After the completion of reaction, the resulting mixture was washed with sodium hydroxide solution, water, Mohr's salt solution, then water, and dried over anhydrous sodium sulfate. The solvent was evaporated and the concentrated was distilled under reduced pressure, there was obtained 6.2 g (yield 77%) of m-trifluoromethylallylbenzene oxide having a boiling point of 110° - 111° C/23 mmHg as colourless liquid.

Workup

  1. customAfter the completion of reaction
  2. washthe resulting mixture was washed with sodium hydroxide solution, water, Mohr's salt solution
  3. dry with materialwater, and dried over anhydrous sodium sulfate
  4. customThe solvent was evaporated
  5. distillationthe concentrated was distilled under reduced pressure

Sources & evidence

ORD record
ord-1410d05f0ff44ecbaabd685194b3b0d4
Source dataset
uspto-grants-1977_12
Patent number
US04062862

Reaction notes

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