Benzoyl Peroxide → HCID 86735272, compound

HRID 461418Notes

Reaction equation

HRID 461418 reaction equation
[O:1]([CH:8]=[CH:9][CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C1C(C(OO)=[O:24])=CC=CC=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)Cl>[O:1]([CH:8]=[CH:9][CH2:10][C:11]12[O:24][CH:16]1[CH:15]=[CH:14][CH:13]=[CH:12]2)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 523077Perbenzoic acidHCID 69857368HCID 69857368, compound

Product 1

HCID 86735272HCID 86735272, compoundYield 58%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

5.8 g of o-phenoxyallylbenzene was added to 70 ml of chloroform solution containing perbenzoic acid prepared from 17 g of benzoyl peroxide and the mixture was allowed to stand at about 5° C for 4 days. The resulting mixture was washed with sodium hydroxide solution, Mohr's salt solution, then water and dried on anhydrous sodium sulfate. The solvent was evaporated and the concentrated was chromatographed over a silica gel, eluted with benzene, there was obtained 3.6 g (yield 58%) of o-phenoxyallylbenzene oxide.

Workup

  1. washThe resulting mixture was washed with sodium hydroxide solution, Mohr's salt solution
  2. dry with materialwater and dried on anhydrous sodium sulfate
  3. customThe solvent was evaporated
  4. customthe concentrated was chromatographed over a silica gel
  5. washeluted with benzene

Sources & evidence

ORD record
ord-83a56de99d574fef8118cb91cfebfb49
Source dataset
uspto-grants-1977_12
Patent number
US04062862

Reaction notes

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