Benzoyl Peroxide → HCID 86735273, compound

HRID 461419Notes

Reaction equation

HRID 461419 reaction equation
[O:1]([CH:8]=[CH:9][CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C1C(C(OO)=[O:24])=CC=CC=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)Cl>[O:1]([CH:8]=[CH:9][CH2:10][C:11]1[CH:12]=[CH:13][CH:14]2[O:24][CH:15]2[CH:16]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 523077Perbenzoic acidHCID 69857368HCID 69857368, compound

Product 1

HCID 86735273HCID 86735273, compoundYield 40%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

To 6.3 g of p-phenoxyallylbenzene was added 45 ml of chloroform solution containing perbenzoic acid prepared from 11 g of benzoylperoxide, and the resulting mixture was allowed to stand at about 5° C for 5 days. The thus obtained solution was washed with 10% sodium hydroxide solution, Mohr's salt solution, then water, and dried over anhydrous sodium sulfate. The solvent was evaporated to obtain the residue. This was chromatographed over a silica gel, and eluted with chloroform, and there was obtained 2.7 g (yield 40%) of p-phenoxyallylbenzene oxide as an oily substance.

Workup

  1. washThe thus obtained solution was washed with 10% sodium hydroxide solution, Mohr's salt solution
  2. dry with materialwater, and dried over anhydrous sodium sulfate
  3. customThe solvent was evaporated
  4. customto obtain the residue
  5. customThis was chromatographed over a silica gel
  6. washeluted with chloroform

Sources & evidence

ORD record
ord-d9881643d4cb4b4fa073b19ac9259992
Source dataset
uspto-grants-1977_12
Patent number
US04062862

Reaction notes

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