Benzoyl Peroxide → HCID 86735274, compound

HRID 461420Notes

Reaction equation

HRID 461420 reaction equation
C1C(C(OO)=[O:8])=CC=CC=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.[CH2:29]([CH:36]=[CH:37][CH2:38][C:39]1[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=1)[C:30]1[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=1>C(Cl)(Cl)Cl>[CH2:38]([CH:37]=[CH:36][CH2:29][C:30]12[O:8][CH:31]1[CH:32]=[CH:33][CH:34]=[CH:35]2)[C:39]1[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=1

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 5187951,1'-(But-2-ene-1,4-diyl)dibenzeneHCID 523077Perbenzoic acid

Product 1

HCID 86735274HCID 86735274, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

To perbenzoic acid in chloroform prepared from 15 g of benzoylperoxide was added 6.0 g of o-benzylallylbenzene and the mixture was allowed to stand at 5° C for 3 days. The mixture was washed with 2% sodium hydroxide solution, Mohr's salt solution, then water, and dried over anhydrous sodium sulfate. The solvent was evaporated to obtain the residue, which was chromatographed over a silica gel, and as eluted with benzene/n-hexane (1/1), there was obtained 1.5 g of o-benzylallylbenzene oxide as an oily substance.

Workup

  1. washThe mixture was washed with 2% sodium hydroxide solution, Mohr's salt solution
  2. dry with materialwater, and dried over anhydrous sodium sulfate
  3. customThe solvent was evaporated
  4. customto obtain the residue, which
  5. customwas chromatographed over a silica gel
  6. washas eluted with benzene/n-hexane (1/1)

Sources & evidence

ORD record
ord-e99f2065959448b79f610e3bd78a3ce1
Source dataset
uspto-grants-1977_12
Patent number
US04062862

Reaction notes

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