Benzoyl Peroxide → HCID 86735275, compound

HRID 461422Notes

Reaction equation

HRID 461422 reaction equation
C([CH:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]1([CH2:15][CH:16]=[CH2:17])[OH:14])C1C=CC=CC=1.[CH:18]1[C:23]([C:24](OO)=[O:25])=[CH:22][CH:21]=[CH:20][CH:19]=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)Cl>[CH2:24]([O:25][CH:17]=[CH:16][CH2:15][C:9]12[O:14][CH:10]1[CH:11]=[CH:12][CH:13]=[CH:8]2)[C:23]1[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=1

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 523077Perbenzoic acidHCID 21393586HCID 21393586, compound

Product 1

HCID 86735275HCID 86735275, compoundYield 70.1%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

5.4 g of o-benzyl-1-allylphenol was added to 600 ml of chloroform solution containing perbenzoic acid prepared from 26.4 g of benzoyl peroxide and the mixture was allowed to stand at about 5° C for 4 days. The reslting mixture was washed with sodium hydroxide solution, water, Mohr's salt solution, then saturated sodium chloride solution, and dried over anhydrous sodium sulfate. The solvent was evaporated to obtain the residue which was distilled under reduced pressure, and there was obtained 4.1 g (yield 70.1%) of o-benzyloxyallylbenzene oxide having a boiling point of 158° to 160° C/5 mmHg as colourless oil.

Workup

  1. washThe reslting mixture was washed with sodium hydroxide solution, water, Mohr's salt solution
  2. dry with materialsaturated sodium chloride solution, and dried over anhydrous sodium sulfate
  3. customThe solvent was evaporated
  4. customto obtain the residue which
  5. distillationwas distilled under reduced pressure

Sources & evidence

ORD record
ord-ed38c409e4be4d36bc756c5234e657f5
Source dataset
uspto-grants-1977_12
Patent number
US04062862

Reaction notes

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