Benzoyl Peroxide → HCID 86735276, compound

HRID 461423Notes

Reaction equation

HRID 461423 reaction equation
[CH2:1]1[O:15][C:4]([C:6]2[CH:11]=[CH:10][CH:9]=[CH:8][C:7]=2[CH2:12][CH:13]=[CH2:14])([CH3:5])[O:3][CH2:2]1.[CH:16]1[C:21]([C:22](OO)=O)=[CH:20][CH:19]=[CH:18][CH:17]=1.C(OOC(=O)C1C=CC=CC=1)(=[O:33])C1C=CC=CC=1>C(Cl)(Cl)Cl>[CH2:1]1[CH2:2][O:3][C:4]([C:6]23[O:33][C:7]2([CH2:12][CH:13]=[CH:14][CH2:22][C:21]2[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=2)[CH:8]=[CH:9][CH:10]=[CH:11]3)([CH3:5])[O:15]1

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 523077Perbenzoic acidHCID 85888700HCID 85888700, compound

Product 1

HCID 86735276HCID 86735276, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

The mixture of 1 g of o-allylacetophenone ethylene ketal, perbenzoic acid prepared from 3.6 g of benzoylperoxide and 100 ml of chloroform was allowed to stand at 5° C for 8 days. The resulting mixture was washed with 10% sodium hydroxide solution, water, Mohr's salt solution, then water, and dried over anhydrous sodium sulfate. The solvent was evaporated to obtain o-(α,α-ethylenedioxyethyl) benzylallylbenzene oxide as pale brownish oily substance.

Workup

  1. washThe resulting mixture was washed with 10% sodium hydroxide solution, water, Mohr's salt solution
  2. dry with materialwater, and dried over anhydrous sodium sulfate
  3. customThe solvent was evaporated

Sources & evidence

ORD record
ord-b742636d961b48d6b9410612fb217e60
Source dataset
uspto-grants-1977_12
Patent number
US04062862

Reaction notes

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