Oxygen → HCID 21393982, compound

HRID 461524Notes

Reaction equation

HRID 461524 reaction equation
[CH:1]1([NH:7][N:8]=[C:9]([CH3:11])[CH3:10])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[O:12]=[O:13]>CCCCCCC>[CH:1]1([N:7]=[N:8][C:9]([O:12][OH:13])([CH3:11])[CH3:10])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1

Participants

5

Reactant 3

HCID 977OxygenHCID 21387191HCID 21387191, compoundHCID 178435160HCID 178435160, compound

Product 1

HCID 21393982HCID 21393982, compoundYield 85%

Reagents, catalysts & solvents 1

HCID 8900HeptaneSolvent

Procedure

A solution of 5.0 grams (0.0324 moles) of acetone cyclohexylhydrazone in 70 grams of heptane was oxidized by passing oxygen through the solution as in Example II. The oxidation was initiated at 35° C. The reaction was followed by gas chromatography, following the disappearance of the cyclohexylhydrazone peak. The reaction was complete in 35 minutes at 35° C. The solution was cooled to 0° and drained into a tared, cooled, polyethylene bottle, weighed and stored at -30° C. The solution weighed 75.1 grams (85% yield).

Workup

  1. customwas initiated at 35° C
  2. temperatureThe solution was cooled to 0°
  3. temperaturecooled
  4. customstored at -30° C

Sources & evidence

ORD record
ord-f071b4d560284213954c0812e78978fa
Source dataset
uspto-grants-1977_12
Patent number
US04063012

Reaction notes

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