Formic Acid → 5,6-Dimethyl-1,2,4-triazolo[3,4-b]benzothiazole

HRID 461852Notes

Reaction equation

HRID 461852 reaction equation
[CH:1](O)=O.[NH:4]([C:6]1[S:7][C:8]2[CH:14]=[CH:13][C:12]([CH3:15])=[C:11]([CH3:16])[C:9]=2[N:10]=1)[NH2:5]>O>[CH3:16][C:11]1[C:9]2[N:10]3[CH:1]=[N:5][N:4]=[C:6]3[S:7][C:8]=2[CH:14]=[CH:13][C:12]=1[CH3:15]

Participants

4

Reactant 2

HCID 284Formic AcidHCID 2049852HCID 2049852, compound

Product 1

HCID 134737055,6-Dimethyl-1,2,4-triazolo[3,4-b]benzothiazole

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A solution of 12 milliliters of formic acid (97-100 percent) and 3.5 grams of 2-hydrazino-4,5-dimethylbenzothiazole was refluxed for 24 hours with stirring. The reaction mixture was then cooled to room temperature and poured into water. The 5,6-dimethyl-s-triazole(3,4-b)benzothiazole compound precipitated and was separated by filtration, 2.6 grams, m.p. 226-8° C.

Workup

  1. customThe 5,6-dimethyl-s-triazole(3,4-b)benzothiazole compound precipitated
  2. customwas separated by filtration, 2.6 grams, m.p. 226-8° C.

Sources & evidence

ORD record
ord-915ecb9a33c84785918f47d055c5827c
Source dataset
uspto-grants-1977_12
Patent number
US04064261

Reaction notes

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